View Publication | CEMHTI CNRS UPR3079 Orléans France

S.Cadars, J.D.Epping, S.Acharya, N.Belman, Y.Golan, B.F.Chmelka, 'Positional and Electronic Order in Semiconducting ZnSe Nanoparticles', Phys. Rev. Lett. 103 136802 (2009) doi:10.1103/physrevlett.103.136802

Size-controlled ZnSe nanoparticles with high extents of atomic positional order are shown to exhibit large size-dependent variations in their local electronic environments. Solid-state 77Se and 67Zn NMR spectra reveal increasingly broad distributions of 77Se and 67Zn environments with decreasing nanoparticle sizes, in contrast with high degrees of atomic positional order established by transmission electron microscopy and x-ray diffraction. First-principles calculations of NMR parameters distinguish between atomic positional and electronic disorder that propagate from the nanoparticle surfaces and yield insights on the order and disorder present.