Conditions Extrêmes et Matériaux : Haute Température et Irradiation
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2014

ACL
doi

V.B.Shirokov, V.M.Kalinchuk, R.A.Shakhovoy, Y.I.Yuzyuk, 'Anomalies of piezoelectric coefficients in barium titanate thin films', Europhysics Lett. 108 47008 (2014) doi:10.1209/0295-5075/108/47008

Modeling of electromechanical devices involves the use of different material coefficients, whose measurement is a difficult task, especially when the problem concerns thin films. Required coefficients of thin films could be found theoretically, using known values of the bulk constants. Electromechanical coefficients of barium titanate thin films are still unknown; therefore, it is expedient to carry out their calculations. We give here the full set of electromechanical coefficients of barium titanate thin films for the whole range of technologically available misfit strains. In the present paper, piezoelectric coefficients as functions of a misfit strain were calculated. It was revealed that piezoelectric coefficients exhibit anomalies at phase boundaries and inside the monoclinic r-phase as well. The obtained results allow finding the required values of the thin-film parameters, varying the misfit strain.