Conditions Extrêmes et Matériaux : Haute Température et Irradiation
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2018

ACL
doi HAL
S.Perruchas, Q.Benito, H.El-Moll, C.Balogh, T.Gacoin, M.Cordier, A.Rakhmatullin, C.Latouche, C.Martineau-Corcos, 'Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate', Chem.-Eur. J. accepted (2018) doi:10.1002/chem.201804377

A copper iodide complex coordinated by three phosphine ligands formulated [Cu2I2(Ph2PC2(C6H4)C2PPh2)3] exhibits luminescence solvatochromic and vapochromic properties. A mechanism based on solvent dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.