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2018
ACL
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Q.Benito, C.Balogh, H.El-Moll, T.Gacoin, M.Cordier, A.Rakhmatullin, C.Latouche, C.Martineau-Corcos, S.Perruchas, 'Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate', Chem.-Eur. J. 24 18868-18872 (2018) doi:10.1002/chem.201804377
A copper iodide complex coordinated by three phosphine ligands formulated [Cu2I2(Ph2PC2(C6H4)C2PPh2)3] exhibits luminescence solvatochromic and vapochromic properties. A mechanism based on solvent dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.
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