Conditions Extrêmes et Matériaux : Haute Température et Irradiation
CEMHTI - UPR3079 CNRS

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Membres du Thème - Members

  F. Fayon PI
  P. Florian PI
  D. Massiot PI
  V. Montouillout PI
  N. Pellerin PI
  V. Sarou-Kanian PI
  E.C. Chesneau PostDoc
  L. Piveteau PostDoc
  M. Porcino PhD st.
  A.R. Richaud Torres Visitor
  A.R. Ridouard PhD st.
  R.S. Sassi PhD st.

Ordre et Désordre dans les Matériaux : Approche RMN
Order and Disorder in Materials : an NMR Approach

Responsable : Valérie Montouillout / List of Publications...

One recent publication...

in press R.Utrera-Melero, B.Huitorel, M.Cordier, J.Y.Mevellec, F.Massuyeau, C.Latouche, C.Martineau-Corcos, * S.Perruchas
'Combining theory and experiment to get insight into the amorphous phase of luminescent mechanochromic copper iodide clusters'
Inorg. Chem. (in press)


NMR Crystallography for inorganic materials

We develop state-of-the-art multinuclear and multidimensional solid-stateNMR spectroscopy that is used in tandem with DFT-calculations and diffraction to investigate the structure and dynamics of inorganic, hybrid and microporous materials. Notably, the combined NMR/DFT approach provides information that is difficult to extract from diffraction data only like isoelectronic substitutions, local disorder, positioning of hydrogens, dynamics.

cristallo

Solid State Imaging

The application of Magnetic Resonance Imaging (MRI) in rigid solids remains challenging as they usually exhibit short transverse relaxation time and strong line broadening which decreases both the sensitivity and the resolution. Magic Angle Spinning (MAS), which averages anisotropic interactions through a macroscopic rotation of the sample, allows obtaining narrow resonances in the solid-state. We show the potentiality of combining MAS and MRI to perform multi-nuclei (1H, 31P, 27Al…) 3D micro-imaging in rigid solid, at very high magnetic field with greatly improved SNR and spatial resolution when compared to static conditions. We apply this methodology on a wide range of materials: polymers, oxide ceramics, biomaterials and hard tissues with spatial resolutions ranging from 30 to 300 microns, at MAS spinning frequencies up to 20 kHz using classical MRI spin-echo or Zero Echo Time (ZTE) sequences. We also developed in vivo localized spectroscopy to study the metabolic profile of drosophila pathological models.

imaging
MAS-MRI 1H-31P 3D images of a mouse tooth

Structure of Glasses

NMR spectroscopy is applied to the oxide glass structure description at a strong level of details thanks to the development of methods exploring heteronuclear and homonuclear correlations. These structural data are essential to characterize the glass properties like chemical durability, thermal stability or behavior to irradiation. For more fundamental interests, these studies explore the ordering of the molecular network at different scales and allow to investigate new glasses formulation and glass instability domains to promote crystallization or phase separation, as interesting roads for new materials investigation (biomaterials, optical devices..). Ab initio calculations and Molecular Dynamics Simulation are then developed in support of NMR spectra simulation and glass structure interpretation enhancement.

glass

High Temperature

We have developed over the last 30 years home-made NMR probes to investigate in-situ high temperature processes. Using a levitation system inside the NMR probe we investigate the structure and dynamics of molten refractory materials up to 2400°C and in contactless conditions. Under static conditions, we are able to investigate materials contained in sealed crucible up to 1400°C, leading to structural investigations of high-temperature liquids such as molten salts as well as aluminosilicate glasses near their glass transition temperature, using our high-field capabilities (20.0 T). This setup has been implemented inside PFG apparatus, allowing the measurement of self-diffusion coefficient in molten salts. The recent acquisition of a laser-heated MAS probe working on our 17.9 T magnet opens the way to the study of phase, glass and solid/liquid transition up to 700°C.

Materials
cooling of an Al2O3 droplet from liquid state

Materials

The group has acquired a great expertise in the characterization of inorganic and hybrid materials.
He participates in a multidisciplinary approach aimed at the development of innovative biomaterials for bone reconstruction. The problem is as well the improvement of the mechanical properties than the development of materials allowing the vectorization of specific contrast or therapeutics agents.
In the context of building materials, the group is particularly interested in understanding the mechanisms that affect the hydration of different kinds of cement: Portland, sulphoaluminate but also cement-substitute as slag or ashes.
Concerning environmental risk of dust explosion and the very large development observed in the domain of additive layer manufacturing (ALM), NMR analyses are applied to the understanding of the explosion and combustion mechanisms for fine metallic powders.

Materials

member of the IR-RMN THC FR3050 CNRS

The delocalized Research Infrastructure "NMR at Very High Fields" (IR-RMN-THC FR3050 CNRS) is a network build on French research teams working with very high fields (typically ≥ 20.0 T) with an internationally recognized expertise. It is part of the the French Research Infrastructure Roadmap.

This network is open to the national, and to a lesser extent international, scientific community of users. It aims at fulfilling the needs of NMR spectroscopists as well as scientist outside of the NMR field. The host laboratories offer access to their state-of-the-art high magnetic field apparatus along with their scientific expertise gained with the most recent technological, methodological and scientific developments in their respective field.


IR-RMN-THC FR3050 CNRS
apply for experiments !!

NMR dedicated programs

dmfit program dmfit editnmr


Nuclei : 1H/ 7Li/ 11B/ 13C/ 14N/ 15N/ 17O/ 19F/ 23Na/ 25Mg/ 27Al/ 29Si/ 31P/ 45Sc/ 63,65Cu/ 67Zn/ 71,69Ga/ 77Se/ 87Rb/ 89Y/ 93Nb/ 113Cd/ 119Sn/ 139La/ 207Pb
Publications des membres | member's publications
Group by   734 records found
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ACL

 
S.Wang, M.Cabrero-Antonino, S.Navalón, C.Cao, A.Tissot, J.Marrot, C.Martineau-Corcos, W.Shepard, H.García, C.Serre
"A robust titanium isophthalate metal-organic framework for visible light photocatalytic CO2 methanation"
Chem in press
ACL

 
Q.Benito, N.Desboeufs, A.Fargues, A.Garcia, F.Massuyeau, C.Martineau-Corcos, T.Devic, S.Perruchas
"A photoactive copper iodide phosphine-based coordination polymer"
New Journal of Chemistry in press
ACL

doi HAL 
J.Fan, V.Sarou-Kanian, X.Yang, M.Diaz-Lopez, F.Fayon, X.Kuang, M.J.Pitcher* and M.Allix*
"La2Ga3O7.5: a metastable ternary melilite with a super-excess of interstitial oxide ions synthesized by direct crystallization of the melt"
Chemistry of Materials in press

ACL

 
Xu (Yvon) Zhang, Giuseppe D.Saldi, Jacques Schott, Julien Bouchez, Marie Kuessner, Valérie Montouillout and Jérôme Gaillardet
"Experimental constraints on Li isotope fractionation during the interaction between kaolinite and seawater"
Geochimica Cosmochimica Acta in press
ACL

 
R.Utrera-Melero, B.Huitorel, M.Cordier, J.Y.Mevellec, F.Massuyeau, C.Latouche, C.Martineau-Corcos, * S.Perruchas
"Combining theory and experiment to get insight into the amorphous phase of luminescent mechanochromic copper iodide clusters"
Inorganic Chemistry in press
ACL

doi HAL 
H.Guo, L.Zhao, C.Martineau-Corcos, F.Fayon, J.Viger-Gravel, H.Awala, P.Boullay, J.Grand, A.Vicente, J.P.Gilson, S.Mintova
"Transformation of Discrete Amorphous Aluminosilicate Nanoparticles into Nanosized Zeolites"
Advanced Materials Interfaces ASAP in press
ACL

doi  
Marie Collin, Babacar Diallo, Hélène Lecoq, Sandra Ory, Elodie Chauvet, Nadia Pellerin
"Chemical durability of lead crystal glass: Comparison of short-term aqueous and atmospheric alteration at 90°C"
International Journal of Applied Glass Sciencs ASAP 2020
ACL

doi  
Assia Mabrouk, Yann Vaills, Nadia Pellerin, Ahmed Bachar
"Structural study of lanthanum sodium aluminoborosilicate glasses by NMR spectroscopy"
Materials Chemistry and Physics 254 123492 2020
ACL

doi HAL 
C.Legein, B.J.Morgan, F.Fayon, T.Koketsu, J.Ma, M.Body, V.Sarou-Kanian, X.K.Wei, M.Heggen, O.J.Borkiewicz, P.Strasser, D.Dambournet
"Atomic Insights into Aluminium-Ion Insertion in Defective Anatase for Batteries"
Angewandte Chemie-International Edition 59 19247-1953 2020

ACLN

 
R.Sassi, F.Fayon, E.Veron, and V.Montouillout
"High Resolution Solid State NMR Structural Study of a Fast-Setting Ternary Binder during its Early Stage Hydration"
Ball, R, Dams, B, Ferrandiz-Mas, V, Ke, X, Paine, K, Tyrer, M & Walker, P (eds) 2019, 39th Cement and Concrete Science Conference 2019. University of Bath, Bath, UK . 2020
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