NMR publications @ CEMHTI
Demande d'Expérience / Ask for experimental time by contacting :
IR-RMN-THC in Infranalytics FR2054 CNRS
or / ou
Pierre Florian
Valérie Montouillout
research group...
Solid State NMR, High Temperature NMR, Oxydes, Hybrids , Disordered Solids
RMN du solide, RMN Haute Température, Oxydes, Hybrides, Matériaux Désordonnés.
Michaël Deschamps
research group...
Molten salts, Structure and Dynamics by Solid State NMR and high temperature NMR
Sels Fondus, Structure et Dynamique par RMN du solide, et RMN Haute Température
Pierre Florian
research group...
High Resolution Solid State and High Temperature NMR
RMN Haute Résolution Solide et Haute Température
Formerly in charge :
Dominique Massiot
Catherine Bessada
Franck Fayon
High Temperature NMR experimental setup
High temperature setup associating CO2 laser heating and crucible or levitation device.
Three of our spectrometers (750MHz, 400MHz and 300MHz) are equiped for laser heated High or Very High Temperature experiments :
-
Closed BN crucible container (Tmax ~1200°C) - application
for molten silicates or molten salts
-
Aerodynamic levitation device (Tmax ~2500°C) for direct laser heating of the sample droplet under oxidizing or neutral atmosphere - application to refractory liquids (aluminates, alumino silicates...)
-
Two CO2 lasers of typically 100 to 150W depending on the system for heating from top / bottom with computer control
| Spectrometers |
Probes & Capabilities |
Bruker
Avance 850MHz
3 channels H/F,X,Y
|
| Type |
Ø |
Vmax |
X range |
Tmin |
Tmax |
X/Y ranges |
| HXY |
1.3 |
67 |
15N ↔ 13C |
-30°C |
+80°C |
27Al/15N, 27Al/29Si, 31P/27Al,
11B/17O-29Si
|
|
HXY
|
2.5
|
35
|
29Si ↔ 31P
|
-30°C
|
+80°C
|
27Al/29Si, 11B/29Si, 11B/27Al,
31P/27Al
|
|
HXY
|
3.2
|
24
|
2D ↔ 31P
|
-140°C
|
+150°C
|
13C/15N, 27Al/29Si, 11B/29Si,
31P/29Si-27Al
|
|
HXY
|
3.2
|
24
|
DBB
|
-140°C
|
+150°C
|
|
|
HX
|
4.0
|
15
|
103Rh ↔ 13C
|
-140°C
|
+150°C
|
n/a
|
|
HX
|
3.0
|
27
|
15N ↔ 31P
|
-140
|
+170
|
15N, 29Si, 79Br, 13C, 27Al,
11B, 31P |
| X |
5.0 |
- |
? |
? |
? |
n/a |
| X |
10.0 |
- |
29Si ↔ 11B |
RT |
+1500°C |
n/a |
|
Bruker
Avance 750MHz
4 channels H/F,X,Y,Z
|
|
Type
|
Ø
|
Vmax
|
X range
|
Tmin
|
Tmax
|
X/Y ranges
|
|
HXY
|
1.3
|
67
|
15N ↔ 13C
|
-30°C
|
+80°C
|
27Al/17O-29Si, 11B/29Si,
11B/27Al
|
|
(H,F)XY
|
1.3
|
67
|
199Hg ↔ 31P
|
-30°C
|
+80°C
|
-
|
|
HXY
|
2.5
|
35
|
33S ↔ 31P
|
-70°C
|
+80°C
|
-
|
|
HXY
|
2.5
|
35
|
? ↔ ?
|
-70°C
|
+80°C
|
31P/17O, 31P/27Al-71Ga,
11B/29Si-27Al, 27Al/29Si,
13C/14N, 2H/14N-15N
|
|
XYZ
|
3.2
|
24
|
31P/27Al/17O
|
?
|
?
|
-
|
|
HXY
|
4.0
|
15
|
? ↔ ?
|
-140°C
|
+150°C
|
11B/29Si, 27Al/17O-29Si,
29Si/17O
|
|
HXY
|
4.0
|
15
|
? ↔ 31P
|
-140°C
|
+150°C
|
31P/27Al-71Ga, 31P/17O-71Ga,
11B/17O
|
|
HX
|
4.0
|
15
|
109Ag ↔ 13C
|
-140°C
|
+150°C
|
-
|
|
XYZ
|
4.0
|
18
|
double coil probe
|
?
|
?
|
|
|
X
|
7.0
|
8
|
89Y ↔ 17O
|
?
|
?
|
-
|
|
X
|
10.0
|
-
|
102MHz ↔ 269MHz
|
RT
|
1300°C
|
-
|
|
Bruker
Avance 400MHz
3 channels H/F,X,Y |
- MAS 2.5mm double tune H/F, X
- MAS 2.5mm triple tune H/F, X, Y
- MAS 3.2mm triple tune H/F, X, Y
- MAS 4.0mm double tune
- High Temperature single tune crucible Tmax ~1300°C / levitation Tmax 2000°C unique design
- High Temperature single tune crucible Tmax ~900°C / Diffusion measurments (50G/cm gradients)
|
Bruker
Avance 300MHz
2 channels H/F,X
|
- MAS 2.5mm single tune X
- MAS 4.0mm double tune H/F, X
- MAS 3.2mm single tune
- MAS 7.0mm double tune
- High Temperature single tune crucible Tmax ~1300°C / levitation Tmax 2000°C
unique design
|